Atomically resolved imaging of highly ordered alternating fluorinated graphene.

نویسندگان

  • Reza J Kashtiban
  • M Adam Dyson
  • Rahul R Nair
  • Recep Zan
  • Swee L Wong
  • Quentin Ramasse
  • Andre K Geim
  • Ursel Bangert
  • Jeremy Sloan
چکیده

One of the most desirable goals of graphene research is to produce ordered two-dimensional (2D) chemical derivatives of suitable quality for monolayer device fabrication. Here we reveal, by focal series exit wave reconstruction (EWR), that C2F chair is a stable graphene derivative and demonstrates pristine long-range order limited only by the size of a functionalized domain. Focal series of images of graphene and C2F chair formed by reaction with XeF2 were obtained at 80 kV in an aberration-corrected transmission electron microscope. EWR images reveal that single carbon atoms and carbon-fluorine pairs in C2F chair alternate strictly over domain sizes of at least 150 nm(2) with electron diffraction indicating ordered domains ≥ 0.16 μm(2). Our results also indicate that, within an ordered domain, functionalization occurs on one side only as theory predicts. In addition, we show that electron diffraction provides a quick and easy method for distinguishing between graphene, C2F chair and fully fluorinated stoichiometric CF 2D phases.

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عنوان ژورنال:
  • Nature communications

دوره 5  شماره 

صفحات  -

تاریخ انتشار 2014